New Strategies for N-Heterocyclic Carbenes Catalyzed Annulations / Springer Theses (PDF)
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This thesis focuses on NHC-catalyzed annulation of nitroalkenes, enals and a,ss-unsaturated carboxylic acids. (1) NHCs were found to be efficient catalysts for the [4+2] annulation of ss-substituted nitroalkenes. The scope of Rauhut-Currier reaction was successfully extended to the most challenging ss-substituted alkenes by this method; (2) Enals were successfully used for [4+2] annulations with azodicarboxylates catalyzed by NHC via ¿-addition. Highly enantiopure tetrahydropyridazinones and ¿-amino acid derivatives could be easily prepared by subsequent transformations of the resulting dihydropyridazinones. (4) The readily available a,ss-unsaturated carboxylic acids were first successfully employed to generate the a,ss-unsaturated acyl azolium intermediates by using NHC for the enantioselective [3+2] and [3+3] annulations.
- Autor: Xiangyu Chen
- 2016, 1st ed. 2017, 123 Seiten, Englisch
- Verlag: Springer-Verlag GmbH
- ISBN-10: 9811028990
- ISBN-13: 9789811028991
- Erscheinungsdatum: 20.12.2016
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