Hydroboration and Organic Synthesis
9-Borabicyclo [3.3.1]nonane (9-BBN)
(Sprache: Englisch)
This book offers a systematic compilation of the vast data available to synthetic chemists. It provides easy access to the necessary information required for chemical transformations.
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Produktinformationen zu „Hydroboration and Organic Synthesis “
This book offers a systematic compilation of the vast data available to synthetic chemists. It provides easy access to the necessary information required for chemical transformations.
Klappentext zu „Hydroboration and Organic Synthesis “
9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN's derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations.
Inhaltsverzeichnis zu „Hydroboration and Organic Synthesis “
- Introduction- General Remarks
- Preparations and Properties
- Kinetic Studies
- Hydroboration
- Synthesis of Alcohols
- Synthesis of Aldehydes and Ketones
- Synthesis of Carboxylic Acids
- Synthesis of Esters
- Synthesis of Nitriles
- Synthesis of (E) -b ,g - Unsaturated amides
- Synthesis of Amines
- Synthesis of Halides
- Synthesis of Dialkylsulfides
- Synthesis of Thiophene oligomeres
- Synthesis of Cyclopropanes and Cyclobutanes
- Synthesis of Borinanes
- Synthesis and Transformation of Butterflyboranes
- Synthesis of a - Bromoboranes
- Synthesis of Borinates
- Synthesis and Transformation of Polymers
- Synthesis of alkali metal 9- boratabicyclo [3.3.1] nonane
- Synthesis of B - R - 9 - BBN not available via hydroboration
- Synthesis of unsaturated compounds
- Reduction
- AsymmetricReduction
- Cleavage of Ethers
- Trans - Metalation
- Separations of isomers
- Diels - Alder reaction
- Suzuki Reaction
- Miscellaneous
Bibliographische Angaben
- Autor: Ranjit S. Dhillon
- 2007, XIII, 586 Seiten, Masse: 16,7 x 24,8 cm, Gebunden, Englisch
- Verlag: Springer, Berlin
- ISBN-10: 3540490752
- ISBN-13: 9783540490753
- Erscheinungsdatum: 18.05.2007
Sprache:
Englisch
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