Zeolites and Catalysis (PDF)

Volume 1 Preface SYNTHESIS MECHANISM: CRYSTAL GROWTH AND NUCLEATION Introduction Theory of Nucleation and Growth Nucleation and Growth in Zeolites Techniques Case Studies Conclusions and Outlook SYNTHESIS APPROACHES Introduction Aluminophosphates Mineralizers Dry Gel Conversion Syntheses Low Water Syntheses Germanium Zeolites Isomorphous Substitution Structure-Directing Agents SDA Modeling Co-Templating Layered Precursors Nonaqueous Solvents Summary and Outlook IONOTHERMAL SYNTHESIS OF ZEOLITES AND OTHER POROUS MATERIALS Introduction Hydrothermal, Solvothermal, and Ionothermal Synthesis Ionothermal Aluminophosphate Synthesis Ionothermal Synthesis of Silica-Based Zeolites Ionothermal Synthesis of Metal Organic Frameworks and Coordination Polymers Ambient Pressure Ionothermal Synthesis The Role of Cation-Templating, Co-Templating, or No Templating The Role of Anion - Structure Induction The Role of Water and Other Mineralizers Unstable Ionic Liquids Summary and Outlook CO-TEMPLATES IN SYNTHESIS OF ZEOLITES Introduction Templating of Dual-Void Structures Crystallization of Aluminophosphate-Type Materials Combined Use of Templating and Pore-Filling Agents Cooperative Structure-Directing Effects of Organic Molecules and Mineralizing Anions Cooperative Structure-Directing Effect of Organic Molecules and Water Control of Crystal Size and Morphology Membrane Systems Use of Co-Templates for Tailoring the Catalytic Activity of Microporous Materials Summary and Outlook MORPHOLOGICAL SYNTHESIS OF ZEOLITES Introduction Morphology of Large Zeolite Crystals Morphology Control of MFI Zeolite Particles Morphological Synthesis by MW Summary and Outlook POST-SYNTHETIC TREATMENT AND MODIFICATION OF ZEOLITES Introduction Direct Synthesis of Zeolites Post-Synthetic Treatment and Modification of Zeolites Summary and Outlook STRUCTURAL CHEMISTRY OF ZEOLITES Introduction Zeolite Structure Types Exemplified by Those Based on the Sodalite Cage The Expanding Library of Zeolite Structures:

Prof. AVELINO CORMA was born in Moncófar, Spain in 1951. He studied Chemistry at the Universidad de Valencia (1967-1973), and received his Ph.D. at the Universidad Complutense de Madrid in 1976. He was a Postdoctoral researcher in the Department of chemical engineering at the Queen?s University (Canada, 1977-79). Prof. Corma is the director of the Instituto de Tecnología Química (UPV-CSIC) at the Universidad Politécnica de Valencia since 1990. His current research field is catalysis, and molecular sieves covering aspects of synthesis, characterization and reactivity in acid-base and redox catalysis. Avelino Corma is co-author of more than 700 articles and 100 patents on these subjects.

Prof. JIRÍ CEJKA was born in Roudnice nad Labem, former Czechoslovakia, in 1960. He studied at the Institute of Chemical Technology in Prague and received his Ph.D. at the J. Heyrovsky Institute of Physical Chemistry and Electrochemistry in Prague in 1988. At present he is a head of the Department of Synthesis and Catalysis at J. Heyrovsky Institute of Physical Chemistry in Prague and lecturer at the Faculty of Natural Sciences of Charles University in Prague. In 2005 he chaired the 3rd FEZA Conference on Zeolites in Prague. His research interests comprise: synthesis of zeolites, mesoporous and novel nano-structured materials, physical chemistry of sorption and catalysis, and investigation of the role of porous catalysts in transformations of hydrocarbons and their derivatives. Jirí Cejka is co-author of about 200 research papers and co-editor of 5 books.

Dr. STACEY I. ZONES is a Research Fellow at Chevron's Energy and Technology Center in Richmond, CA, USA. He is the senior researcher in a group which strives to invent and explore newer zeolites and then follow through in finding applications for their use, ways to tailor their properties and methods to develop more econmical routes to introduce them into the commercial world. The group also looks for novel applications of

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