Photochemistry of Organic Compounds / Postgraduate Chemistry Series (PDF)
From Concepts to Practice
(Sprache: Englisch)
Photochemistry of Organic Compounds: From Concepts to
Practice provides a hands-on guide demonstrating the underlying
principles of photochemistry and, by reference to a range of
organic reaction types, its effective use in the synthesis of new
organic...
Practice provides a hands-on guide demonstrating the underlying
principles of photochemistry and, by reference to a range of
organic reaction types, its effective use in the synthesis of new
organic...
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Photochemistry of Organic Compounds: From Concepts to
Practice provides a hands-on guide demonstrating the underlying
principles of photochemistry and, by reference to a range of
organic reaction types, its effective use in the synthesis of new
organic compounds and in various applications.
The book presents a complete and methodical approach to the
topic,
* Working from basic principles, discussing key techniques and
studies of reactive intermediates, and illustrating synthetic
photochemical procedures.
* Incorporating special topics and case studies covering various
applications of photochemistry in chemistry, environmental
sciences, biochemistry, physics, medicine, and industry.
* Providing extensive references to the original literature and
to review articles.
* Concluding with a chapter on retrosynthetic photochemistry,
listing key reactions to aid the reader in designing their own
synthetic pathways.
This book will be a valuable source of information and
inspiration for postgraduates as well as professionals from a wide
range of chemical and natural sciences.
Practice provides a hands-on guide demonstrating the underlying
principles of photochemistry and, by reference to a range of
organic reaction types, its effective use in the synthesis of new
organic compounds and in various applications.
The book presents a complete and methodical approach to the
topic,
* Working from basic principles, discussing key techniques and
studies of reactive intermediates, and illustrating synthetic
photochemical procedures.
* Incorporating special topics and case studies covering various
applications of photochemistry in chemistry, environmental
sciences, biochemistry, physics, medicine, and industry.
* Providing extensive references to the original literature and
to review articles.
* Concluding with a chapter on retrosynthetic photochemistry,
listing key reactions to aid the reader in designing their own
synthetic pathways.
This book will be a valuable source of information and
inspiration for postgraduates as well as professionals from a wide
range of chemical and natural sciences.
Inhaltsverzeichnis zu „Photochemistry of Organic Compounds / Postgraduate Chemistry Series (PDF)“
1. Introduction. 1.1 Who's Afraid Of Photochemistry? 1.2 Electromagnetic Radiation. 1.3 Perception Of Colour. 1.4 Electronic States: Elements Of Molecular Quantum Mechanics. 1.5 Problems. 2. A Crash Course In Photophysics And A Classification Of Primary Photoreactions. 2.1 Photophysical Processes. 2.2 Energy Transfer, Quenching and Sensitization. 2.3 A Classification of Photochemical Reaction Pathways. 2.4 Problems. 3. Techniques And Methods. 3.1 Light Sources, Filters, and Detectors. 3.2 Preparative Irradiation. 3.3 Absorption Spectra. 3.4 Steady-State Emission Spectra and Their Correction. 3.5 Time-Resolved Luminescence. 3.6 Absorption And Emission Spectroscopy With Polarized Light. 3.7 Flash Photolysis. 3.8 Time-Resolved IR and Raman Spectroscopy. 3.9 Quantum Yields. 3.10 Low-Temperature Studies; Matrix Isolation. 3.11 Photoacoustic Calorimetry. 3.12 Two-Photon Absorption Spectroscopy. 3.13 Single-Molecule Spectroscopy. 3.14 Problems. 4. Quantum Mechanical Models of Electronic Excitation and Photochemical Reactivity. 4.1 Boiling Down The Schr(TM)Dinger Equation. 4.2 HSckel Molecular Orbital Theory. 4.3 HMO Perturbation Theory. 4.4 Symmetry Considerations. 4.5 Simple Quantum Chemical Models of Electronic Excitation. 4.6 Pairing Theorems and Dewar's PMO Theory. 4.7 The Need for Improvement; SCF, CI And DFT Calculations. 4.8 Spin-Orbit Coupling. 4.9 Theoretical Models of Photoreactivity, Correlation Diagrams. 4.10 Problems. 4.11 Appendix. 5. Photochemical Reaction Mechanisms and Reaction Intermediates. 5.1 What is a Reaction Mechanism? 5.2 Electron Transfer. 5.3 Proton Transfer. 5.4 Primary Photochemical Intermediates: Examples and Concepts. 5.5 Photoisomerization of Double Bonds. 5.6 Chemiluminescence and Bioluminescence. 5.7 Problems. 6. Chemistry Of Excited Molecules. 6.1 Alkenes And Alkynes. 6.2 Aromatic Compounds. 6.3 Oxygen Compounds. 6.4 Nitrogen Compounds. 6.5 Sulphur Compounds. 6.6 Halogen Compounds. 6.7 Molecular Oxygen. 6.8 Photosensitizers,
... mehr
Photoinitiators and Photocatalysts. 7. Retrosynthetic Photochemistry. 8. Information Sources, Tables. 9. Index. 10. References.
... weniger
Autoren-Porträt von Petr Klán, Jakob Wirz
Petr Klán is Professor of Organic Chemistry in the Departmentof Chemistry, Masaryk University, Brno, Czech Republic
Jakob Wirz is Professor of Physical Chemistry in the Department
of Chemistry, University of Basel, Switzerland
Bibliographische Angaben
- Autoren: Petr Klán , Jakob Wirz
- 2009, 1. Auflage, 582 Seiten, Englisch
- Verlag: John Wiley & Sons
- ISBN-10: 1444300008
- ISBN-13: 9781444300000
- Erscheinungsdatum: 26.01.2009
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