Mass Spectrometric Screening of Chiral Catalysts (PDF)
(Sprache: Englisch)
The principle of microscopic reversibility serves as the basis of a novel screening method for the evaluation of chiral catalysts within asymmetric allylic substitution reactions. Monitoring the back reaction of quasienantiomeric products by electrospray...
sofort als Download lieferbar
eBook (pdf)
Fr. 42.90
inkl. MwSt.
- Kreditkarte, Paypal, Rechnung
- Kostenloser tolino webreader
Produktdetails
Produktinformationen zu „Mass Spectrometric Screening of Chiral Catalysts (PDF)“
The principle of microscopic reversibility serves as the basis of a novel screening method for the evaluation of chiral catalysts within asymmetric allylic substitution reactions. Monitoring the back reaction of quasienantiomeric products by electrospray ionisation mass spectrometry (ESI-MS) reveals the intrinsic enantioselectivity of palladium catalysts in the nucleophilic addition step and thus in the overall substitution process. As only the intrinsic selectivity is measured in the screening the effects of unselective background reaction, catalytically active
impurities and ligand dissociation do not alter the results, in contrast to product analysis.
The method was successfully applied to both linear diaryl and carbocyclic substrates.
Furthermore, a protocol for the simultaneous screening of catalyst mixtures was developed, offering new possibilities for high-throughput catalyst analysis.
impurities and ligand dissociation do not alter the results, in contrast to product analysis.
The method was successfully applied to both linear diaryl and carbocyclic substrates.
Furthermore, a protocol for the simultaneous screening of catalyst mixtures was developed, offering new possibilities for high-throughput catalyst analysis.
Bibliographische Angaben
- 2008, 288 Seiten, Englisch
- Verlag: Cuvillier Verlag
- ISBN-10: 3736926146
- ISBN-13: 9783736926141
- Erscheinungsdatum: 09.06.2008
Abhängig von Bildschirmgrösse und eingestellter Schriftgrösse kann die Seitenzahl auf Ihrem Lesegerät variieren.
eBook Informationen
- Dateiformat: PDF
- Grösse: 1.69 MB
- Ohne Kopierschutz
- Vorlesefunktion
Sprache:
Englisch
Family Sharing
eBooks und Audiobooks (Hörbuch-Downloads) mit der Familie teilen und gemeinsam geniessen. Mehr Infos hier.
Kommentar zu "Mass Spectrometric Screening of Chiral Catalysts"
0 Gebrauchte Artikel zu „Mass Spectrometric Screening of Chiral Catalysts“
Zustand | Preis | Porto | Zahlung | Verkäufer | Rating |
---|
Schreiben Sie einen Kommentar zu "Mass Spectrometric Screening of Chiral Catalysts".
Kommentar verfassen