Handbook of Cyclization Reactions, 2 Vols.

CYCLOMETALLATIONIntroductionTitanium-Catalyzed CyclizationsZirconium-Catalyzed CyclizationsRuthenium-Catalyzed CyclizationsCobalt-Catalyzed CyclizationsRhodium-Catalyzed CyclizationsIridium-Catalyzed CyclizationsNickel-Catalyzed CyclizationsPalladium-Catalyzed CyclizationsConclusions and PerspectivesExperimental: Selected ProceduresTRANSITION METAL CATALYZED CYCLIZATION REACTIONS OF FUNCTIONALIZED ALKENES, ALKYNES, AND ALLENESIntroductionCyclization Reactions of AlkenesCyclization Reactions of AlkynesCyclization Reactions of AllenesConclusion and PerspectiveExperimental: Selected ProceduresRING-CLOSING METATHESIS OF DIENES AND ENYNESIntroductionRing-Closing Metathesis of DienesRing-Closing Metathesis of EnynesPerspectiveExperimental: Selected ProcedureRING-CLOSING METATHESIS OF ALKYNESIntroductionAlkyne MetathesisRing-Closing Alkyne Metathesis as a Synthetic StrategyCatalyst Systems for Ring-Closing Alkyne MetathesisComplex Molecule Synthesis using Ring-Closing Alkyne MetathesisRing-Closing Alkyne Metathesis within Transition Metal Coordination SpheresCyclo Dimerizations, Trimerizations, and OligomerizationsConclusions and PerspectivesExperimental: Selected ProceduresVOLUME 2TRANSITION-METAL-CATALYZED CYCLOISOMERIZATIONS AND NUCLEOPHILIC CYCLIZATION OF ENYNESIntroductionCycloisomerizations of 1,n-EnynesAddition of Nucleophiles to 1,n-EnynesSkeletal Rearrangement of 1,n-EnynesSummary and OutlookExperimental: Selected ProceduresCYCLOPROPANATION, EPOXIDATION AND AZIRIDINATION REACTIONSIntroductionCyclopropanationEpoxidationsAziridinationsExperimental: Selected ProceduresCYCLIZATION OF CYCLOPROPANE- OR CYCLOPROPENE-CONTAINING COMPOUNDSIntroductionCycloisomerization ReactionsCycloaddition ReactionsMulticomponent Cyclization ReactionsCyclization Involving Miscellaneous and Cascade ReactionsExperimental: Selected ProceduresTRANSITION METAL-CATALYZED RING EXPANSION CYCLIZATION REACTIONSIntroductionPalladium-Catalyzed Ring ExpansionsRing Expansions with Other Transition MetalsConclusionExperimental: Selected ProceduresHYDROMETALLATION-INITIATED CYCLIZATION REACTIONSIntroductionSelf-Feeding CyclizationCyclization Tied by Outsourcing ReagentsCascade Reactions Incorporating COConclusionExperimental: Selected ProceduresCATALYTIC DIPOLAR CYCLOADDITIONS OF ALKYNES WITH AZIDES AND NITRILE OXIDESIntroductionAzide-Alkyne Cycloaddition: BasicsCopper-Catalyzed CycloadditionsRuthenium-Catalyzed CycloadditionsExperimental: Selected ProceduresELECTROPHILIC CYCLIZATIONSIntroductionMechanism, Regio- and StereoselectivityHalocyclizationsSelenocyclizationsConclusion and PerspectivesExperimental: Selected ProceduresCYCLIZATIONS BASED ON C-H ACTIVATIONIntroductionAryl C-H Bond ActivationAlkyl C-H Bond ActivationExperimental: Selected ProceduresFRIEDEL-CRAFTS TYPE CYCLIZATIONSIntroductionClassic Intramolecular Friedel-Crafts CyclizationsRCFC Reactions via Activation of Carbonyl Derivatives and AlcoholsRCFC Reactions of C-C Pi bondsMiscellaneous ReactionsCatalytic Enantioselective RCFC ReactionsConclusionExperimental: Selected ProceduresMACROLACTONES AND MACROLACTAMSMacrolactonesMacrolactamsConclusion and PerspectivesExperimental: Selected ProceduresFREE RADICAL CYCLIZATION REACTIONSRadical Cyclizations: General DefinitionDifferent Methods for Radical CyclizationsAnnulation ReactionsDiastereoselective Radical CyclizationEnantioselective Radical CyclizationApplications of Radical Cyclizations in Natural Product SynthesisExperimental: Selected ProceduresPHOTOCYCLIZATION REACTIONSIntroductionSeveral Ways to Initiate PhotocyclizationNorrish Type II Initiated Reactions: H TransferPhotoinduced Electron Transfer CyclizationsPi-Pi-InteractionsPi6-PhotocyclizationExperimental: Selected ProceduresASYMMETRIC ORGANOCATALYZED CYCLIZATION REACTIONSIntroductionEnamine-Catalyzed Asymmetric Cyclization ReactionsIminium-Catalyzed Cyclization ReactionsSequential Catalysis with Chiral Amines for Domino Cyclization ReactionsBronsted Acid-Catalyzed Asymmetric Cyclization ReactionsLewis Base-Catalyzed Asymmetric CycloadditionsAsymmetric Cyclization Reactions by Bifunctional CatalystsAsymmetric Cyclizations Catalyzed by Chiral Nucleophilic CarbenesConclusionExperimental: Selected Procedures