Colloidal Crystals of Spheres and Cubes in Real and Reciprocal Space / Springer Theses (PDF)
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This thesis presents an in-depth study on the effect of colloidal particle shape and formation mechanism on self-organization and the final crystal symmetries that can be achieved. It demonstrates how state-of-the-art X-ray diffraction techniques can be used to produce detailed characterizations of colloidal crystal structures prepared using different self-assembly techniques, and how smart systems can be used to investigate defect formation and diffusion in-situ. One of the most remarkable phenomena exhibited by concentrated suspensions of colloidal particles is the spontaneous self-organization into structures with long-range spatial and/or orientational orders. The study also reveals the subtle structural variations that arise by changing the particle shape from spherical to that of a rounded cube. In particular, the roundness of the cube corners, when combined with the self-organization pathway, convective assembly or sedimentation, was shown to influence the final crystal symmetries.
- Autor: Janne-Mieke Meijer
- 2015, 2015, 155 Seiten, Englisch
- Verlag: Springer-Verlag GmbH
- ISBN-10: 3319148095
- ISBN-13: 9783319148090
- Erscheinungsdatum: 11.06.2015
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- Grösse: 7.85 MB
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