Non-Noble Metal Catalysis

COMPOUNDS AND CARBON DIOXIDE Introduction Hydrosilylation of Aldehydes and Ketones Reduction of Imines and Reductive Amination of Carbonyl Compounds Reduction of Carboxylic Acid Derivatives Hydroelementation of Carbon Dioxide Conclusion REACTIVE INTERMEDIATES AND MECHANISM IN IRON-CATALYZED CROSS-COUPLING Introduction Cross-Coupling Catalyzed by Simple Iron Salts TMEDA in Iron-Catalyzed Cross-Coupling NHCs in Iron-Catalyzed Cross-Coupling Phosphines in Iron-Catalyzed Cross-Coupling Future Outlook RECENT ADVANCES IN COBALT-CATALYZED CROSS-COUPLING REACTIONS Introduction Cobalt-Catalyzed C-C Coupling Through a C-H Activation Approach Cobalt-Catalyzed C-C Couplings Using a Preactivated Substrate Approach (Aryl Halides and Pseudohalides) Cobalt-Catalyzed C-X Couplings Using C-H Activation Approaches Cobalt-Catalyzed C-X Couplings Using a Preactivated Substrate Approach (Aryl Halides and Pseudohalides) Miscellaneous Conclusions and Future Prospects TRIFLUOROMETHYLATION AND RELATED REACTIONS Trifluoromethylation Reactions Trifluoromethylthiolation Reactions Perfluoroalkylation Reactions Conclusion CATALYTIC OXYGENATION OF C=C AND C-H BONDS Introduction Oxygenation of C=C Bonds Oxygenation of C-H Bonds Conclusions and Outlook ORGANOMETALLIC CHELATION-ASSISTED C-H FUNCTIONALIZATION Introduction C-C Bond Formation via C-H Activation C-Heteroatom Formation via C-H Activation Conclusions CATALYTIC WATER OXIDATION: WATER OXIDATION TO O2 MEDIATED BY 3D TRANSITION METAL COMPLEXES Water Oxidation - From Insights into Fundamental Chemical Concepts to Future Solar Fuels ModelWell-DefinedWater Oxidation Catalysts Conclusion and Outlook BASE-METAL-CATALYZED HYDROGEN GENERATION FROM CARBON- AND BORON NITROGEN-BASED SUBSTRATES Introduction Hydrogen Generation from Formic Acid Hydrogen Generation from Alcohols Hydrogen Storage in Liquid Organic Hydrogen Carriers Dehydrogenation of Ammonia Borane and Amine Boranes Conclusion MOLECULAR CATALYSTS FOR PROTON REDUCTION BASED ON NON-NOBLE METALS Introduction Iron and Nickel Catalysts Other Non-Noble Metal-Based Catalysts: Co, Mn, Cu, Mo, and W Conclusion NONREDUCTIVE REACTIONS OF CO2 MEDIATED BY COBALT CATALYSTS: CYCLIC AND POLYCARBONATES Introduction Cocatalysts for CO2/Epoxide Couplings: Salen-Based Systems Co-Porphyrins as Catalysts for Epoxide/CO2 Coupling Cocatalysts Based on Other N4-Ligated and Related Systems Aminophenoxide-Based Co Complexes Conclusion and Outlook DINITROGEN REDUCTION Introduction Activation of N2 Reduction of N2 to Ammonia Reduction of N2 to Silylamines Conclusions and Outlook Index