Designing Models to Elucidate Radical Reaction Mechanisms
Model Studies of Diol-dehydratase-catalyzed Reactions and Excess Electron Transfer
(Sprache: Englisch)
This book talks about how to design a model organic molecule to study radical reaction mechanisms. The molecule must incorporate a radical-generating element that can give the target radical under certain condition, such as heat or light (e.g., laser), and...
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This book talks about how to design a model organic molecule to study radical reaction mechanisms. The molecule must incorporate a radical-generating element that can give the target radical under certain condition, such as heat or light (e.g., laser), and a radical-detecting element that can detect the product radical once the reaction occurs. Both the radical-generating and the radical-detecting processes must be fast enough to allow accurate kinetic measurements. This model-designing strategy was applied to mimic the radical reactions catalyzed by diol dehydratase (DD) and the excess electron transfer (EET, or reductive electron transfer) process, where radical anions are the intermediates, in biological molecules. The designing process was illustrated during the studies of DD-catalyzed reactions and EET.
Autoren-Porträt von Libin Xu
Xu, LibinDr. Libin Xu obtained his B.Sc. in Chemistry from Nankai University, China, in 2002 and his Ph.D. from the University of Illinois at Chicago under Dr. Martin Newcomb in 2007. His research interests involve general radical reactions, electron transfer reactions in nature, and radical-catalyzed peroxidation of biological molecules.
Bibliographische Angaben
- Autor: Libin Xu
- 2008, 188 Seiten, Masse: 15 x 22 cm, Kartoniert (TB), Englisch
- Verlag: VDM Verlag Dr. Müller e.K.
- ISBN-10: 3639051505
- ISBN-13: 9783639051506
Sprache:
Englisch
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