Chemical Thermodynamics
for Process Simulation
(Sprache: Englisch)
This is the only book to apply thermodynamics to real-world process engineering problems, explaining the thermodynamics behind simulations from the view of academic and industrial authors to users of simulation programs. It comprises numerous solved...
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Produktinformationen zu „Chemical Thermodynamics “
This is the only book to apply thermodynamics to real-world process engineering problems, explaining the thermodynamics behind simulations from the view of academic and industrial authors to users of simulation programs. It comprises numerous solved examples, which simplify the understanding of the often complex calculation procedures, and discusses their advantages and disadvantages. The text also includes such special models as for formaldehyde, polymers, and associating compounds. Estimation methods for thermophysical properties and phase equilibria and thermodynamics of alternative separation processes are covered, as are new developments from recent years.
Recipes for the procedure are given at the end of each chapter, and further small programs are available via the Internet, such as MathCad and Excel files.
While written for an advanced level, the text is easy to understand for every chemical engineer and chemist with a basic education in thermodynamics and phase equilibria, teaching students the engineering perspective of thermodynamics but also of interest to all companies active in chemistry, pharmacy, oil and gas processing, petrochemistry, refinery, food production, environmental protection and engineering.d examples, which simplify the understanding of the often complex calculation procedures, and discusses their advantages and disadvantages. The text also includes such special models as for formaldehyde, polymers, and associating compounds. Estimation methods for thermophysical properties and phase equilibria and thermodynamics of alternative separation processes are covered, as are new developments from recent years.
Recipes for the procedure are given at the end of each chapter, and further small programs are available via the Internet, such as MathCad and Excel files.
While written for an advanced level, the text is easy to understand for every chemical engineer and chemist with a basic education in thermodynamics and phase equil
Recipes for the procedure are given at the end of each chapter, and further small programs are available via the Internet, such as MathCad and Excel files.
While written for an advanced level, the text is easy to understand for every chemical engineer and chemist with a basic education in thermodynamics and phase equilibria, teaching students the engineering perspective of thermodynamics but also of interest to all companies active in chemistry, pharmacy, oil and gas processing, petrochemistry, refinery, food production, environmental protection and engineering.d examples, which simplify the understanding of the often complex calculation procedures, and discusses their advantages and disadvantages. The text also includes such special models as for formaldehyde, polymers, and associating compounds. Estimation methods for thermophysical properties and phase equilibria and thermodynamics of alternative separation processes are covered, as are new developments from recent years.
Recipes for the procedure are given at the end of each chapter, and further small programs are available via the Internet, such as MathCad and Excel files.
While written for an advanced level, the text is easy to understand for every chemical engineer and chemist with a basic education in thermodynamics and phase equil
Klappentext zu „Chemical Thermodynamics “
This is the only book to apply thermodynamics to real-world process engineering problems, explaining the thermodynamics behind simulations from the view of academic and industrial authors to users of simulation programs. It comprises numerous solved examples, which simplify the understanding of the often complex calculation procedures, and discusses their advantages and disadvantages. The text also includes such special models as for formaldehyde, polymers, and associating compounds. Estimation methods for thermophysical properties and phase equilibria and thermodynamics of alternative separation processes are covered, as are new developments from recent years.For a deeper understanding additional problems are given at the end of each chapter. To solve the complex problems prepared Mathcad files, Excel files or the DDBSP Explorer version can be accessed via the Internet.
While written for an advanced level, the text is easy to understand for every chemical engineer and chemist with a basic education in thermodynamics and phase equilibria, teaching students the engineering perspective of thermodynamics but also of interest to all companies active in chemistry, pharmacy, oil and gas processing, petrochemistry, refinery, food production, environmental protection and engineering.
This is the only book to apply thermodynamics to real-world process engineering problems, explaining the thermodynamics behind simulations from the view of academic and industrial authors to users of simulation programs. It comprises numerous solved examples, which simplify the understanding of the often complex calculation procedures, and discusses their advantages and disadvantages. The text also includes such special models as for formaldehyde, polymers, and associating compounds. Estimation methods for thermophysical properties and phase equilibria and thermodynamics of alternative separation processes are covered, as are new developments from recent years.
Recipes for the procedure are given at the end of each chapter, and further small programs are available via the Internet, such as MathCad and Excel files.
While written for an advanced level, the text is easy to understand for every chemical engineer and chemist with a basic education in thermodynamics and phase equilibria, teaching students the engineering perspective of thermodynamics but also of interest to all companies active in chemistry, pharmacy, oil and gas processing, petrochemistry, refinery, food production, environmental protection and engineering.d examples, which simplify the understanding of the often complex calculation procedures, and discusses their advantages and disadvantages. The text also includes such special models as for formaldehyde, polymers, and associating compounds. Estimation methods for thermophysical properties and phase equilibria and thermodynamics of alternative separation processes are covered, as are new developments from recent years.
Recipes for the procedure are given at the end of each chapter, and further small programs are available via the Internet, such as MathCad and Excel files.
While written for an advanced level, the text is easy to understand for every chemical engineer and chemist with a basic education in thermodynamics and phase equil
Recipes for the procedure are given at the end of each chapter, and further small programs are available via the Internet, such as MathCad and Excel files.
While written for an advanced level, the text is easy to understand for every chemical engineer and chemist with a basic education in thermodynamics and phase equilibria, teaching students the engineering perspective of thermodynamics but also of interest to all companies active in chemistry, pharmacy, oil and gas processing, petrochemistry, refinery, food production, environmental protection and engineering.d examples, which simplify the understanding of the often complex calculation procedures, and discusses their advantages and disadvantages. The text also includes such special models as for formaldehyde, polymers, and associating compounds. Estimation methods for thermophysical properties and phase equilibria and thermodynamics of alternative separation processes are covered, as are new developments from recent years.
Recipes for the procedure are given at the end of each chapter, and further small programs are available via the Internet, such as MathCad and Excel files.
While written for an advanced level, the text is easy to understand for every chemical engineer and chemist with a basic education in thermodynamics and phase equil
Inhaltsverzeichnis zu „Chemical Thermodynamics “
INTRODUCTIONPVT BEHAVIOR OF PURE COMPONENTS General Description Caloric Properties
Ideal Gases
Real Fluids
Equations of State
CORRELATION AND ESTIMATION OF PURE COMPONENT PROPERTIES
Characteristic Physical Property Constants
Temperature-Dependent Properties
Correlation and Estimation of Transport Properties
PROPERTIES OF MIXTURES
Property Changes of Mixing
Partial Molar Properties
Gibbs-Duhem Equation
Ideal Mixture of Ideal Gases
Ideal Mixture of Real Fluids
Excess Properties
Fugacity in Mixtures
Activity and Activity Coefficient
Application of Equations of State to Mixtures
PHASE EQUILIBRIA IN FLUID SYSTEMS Thermodynamic Fundamentals
Application of Activity Coefficient Models
Calculation of Vapor-Liquid Equilibria Using gE-Models
Fitting of gE-Model Parameters
Calculation of Vapor-Liquid Equilibria Using Equations of State
Conditions for the Occurrence of Azeotropic Behavior
Solubility of Gases in Liquids
Liquid-Liquid Equilibria
Predictive Models
CALORIC PROPERTIES
Caloric Equations of State
Enthalpy Description in Process Simulation Programs
Caloric Properties in Chemical Reactions
The G-Minimization Technique
ELECTROLYTE SOLUTIONS
Introduction
Thermodynamics of Electrolyte Solutions
Activity Coefficient Models for Electrolyte Solutions
Dissociation Equilibria
Influence of Salts on the Vapor-Liquid Equilibrium Behavior
Complex Electrolyte Systems
SOLID-LIQUID EQUILIBRIA
Thermodynamic Relations for the Calculation of Solid-Liquid Equilibria
Salt Solubility
Solubility of Solids in Supercritical Fluids
MEMBRANE PROCESSES
Osmosis
Pervaporation
POLYMER THERMODYNAMICS
Introduction
gE-models
Equations of State
Influence of Polydispersity
APPLICATIONS OF THERMODYNAMICS IN SEPARATION TECHNOLOGY
Verification of Model Parameters Prior to Process Simulation
Investigation of Azeotropic Points in Multicomponent Systems
Residue Curves, Distillation Boundaries, and Distillation Regions
Selection of
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Entrainers for Azeotropic and Extractive Distillation
Selection of Solvents for Other Separation Processes
Examination of the Applicability of Extractive Distillation for the Separation of Aliphatics from Aromatics
ENTHALPY OF REACTION AND CHEMICAL EQUILIBRIA
Enthalpy of Reaction
Chemical Equilibrium
Multiple Chemical Reaction Equilibria
SPECIAL APPLICATIONS
Formaldehyde Solutions
Vapor Phase Association
PRACTICAL APPLICATIONS
Flash
Joule-Thomson Effect
Adiabatic Compression and Expansion
Pressure Relief
Limitations of Equilibrium Thermodynamics
INTRODUCTION TO THE COLLECTION OF EXAMPLE PROBLEMS
Mathcad Examples
Examples Using the Dortmund Data Bank (DDB) and the Integrated Software Package DDBSP
Examples Using Microsoft Excel and Microsoft Office VBA
APPENDIX A Pure Component Parameters
APPENDIX B Coefficients for High Precision Equations of State
APPENDIX C Useful Derivations
APPENDIX D Standard Thermodynamic Properties for Selected Electrolyte Compounds
APPENDIX E Regression Technique for Pure Component Data
APPENDIX F Regression Techniques for Binary Parameters Appendix G Ideal Gas Heat Capacity Polynomial Coefficients for Selected Compounds
APPENDIX H UNIFAC Parameters
APPENDIX I Modified UNIFAC Parameters
APPENDIX J PSRK Parameters
APPENDIX K VTPR Parameters
Index
Selection of Solvents for Other Separation Processes
Examination of the Applicability of Extractive Distillation for the Separation of Aliphatics from Aromatics
ENTHALPY OF REACTION AND CHEMICAL EQUILIBRIA
Enthalpy of Reaction
Chemical Equilibrium
Multiple Chemical Reaction Equilibria
SPECIAL APPLICATIONS
Formaldehyde Solutions
Vapor Phase Association
PRACTICAL APPLICATIONS
Flash
Joule-Thomson Effect
Adiabatic Compression and Expansion
Pressure Relief
Limitations of Equilibrium Thermodynamics
INTRODUCTION TO THE COLLECTION OF EXAMPLE PROBLEMS
Mathcad Examples
Examples Using the Dortmund Data Bank (DDB) and the Integrated Software Package DDBSP
Examples Using Microsoft Excel and Microsoft Office VBA
APPENDIX A Pure Component Parameters
APPENDIX B Coefficients for High Precision Equations of State
APPENDIX C Useful Derivations
APPENDIX D Standard Thermodynamic Properties for Selected Electrolyte Compounds
APPENDIX E Regression Technique for Pure Component Data
APPENDIX F Regression Techniques for Binary Parameters Appendix G Ideal Gas Heat Capacity Polynomial Coefficients for Selected Compounds
APPENDIX H UNIFAC Parameters
APPENDIX I Modified UNIFAC Parameters
APPENDIX J PSRK Parameters
APPENDIX K VTPR Parameters
Index
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Autoren-Porträt von Jürgen Gmehling, Bärbel Kolbe, Michael Kleiber, Jürgen Rarey
Prof. Dr. Jürgen Gmehling, born 1946, is Professor of Technical Chemistry at the Carl von Ossietzky University of Oldenburg in Germany. His research interests focus on the computerized design and optimization of chemical processes, investigating separation processes and thermophysical properties. The various predictive thermodynamic models such as the group contribution methods UNIFAC, modified UNIFAC and LIFAC or the group contribution equation of state PSRK and VTPR developed in his research group with the help of the Dortmund Data Bank are used worldwide by a large number of chemical engineers during their daily work with process simulators. He is author of some 50 books, including text books on thermal process engineering, thermodynamics, and unit operations, as well as more than 300 papers in scientific journals. He received the Arnold-Eucken award of the GVC. Apart from his professorship, he is CEO of the company DDBST GmbH founded in 1989, responsible for the continuous update of the Dortmund Data Bank and its integrated software package, as well as director of the Laboratory for Thermophysical Properties (LTP) GmbH, which was founded in 1999. He currently also serves as an elected member in three scientific boards of GVC and DECHEMA, and in the Editorial Advisory Board of four international scientific journals.tive thermodynamic models such as the group contribution methods UNIFAC, modified UNIFAC and LIFAC or the group contribution equation of state PSRK and VTPR developed in his research group with the help of the Dortmund Data Bank are used worldwide by a large number of chemical engineers during their daily work with process simulators. He is author of some 50 books, including text books on thermal process engineering, thermodynamics, and unit operations, as well as more than 300 papers in scientific journals. He received the Arnold-Eucken award of the GVC. Apart from his professorship, he is CEO of the company DDBST GmbH founded in 1989, responsible for
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the continuous update of the Dortmund Data Bank
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Bibliographische Angaben
- Autoren: Jürgen Gmehling , Bärbel Kolbe , Michael Kleiber , Jürgen Rarey
- 2012, 1. Auflage, XXVI, 735 Seiten, 301 Schwarz-Weiss-Abbildungen, Masse: 18,2 x 25 cm, Gebunden, Englisch
- Verlag: Wiley-VCH
- ISBN-10: 3527312773
- ISBN-13: 9783527312771
Sprache:
Englisch
Rezension zu „Chemical Thermodynamics “
?If you are interested in detailed and accessible thermodynamics, start and finish with this book.??Chemistry in Australia, September 2012
Pressezitat
?If you are interested in detailed and accessible thermodynamics, start and finish with this book.??Chemistry in Australia, September 2012
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